Probabilistic approach to water heat capacity
Abstract
properties of water depend on the binding energy and relative time of the connection
between the molecules in water, as well as derivatives of these quantities on temperature. Grade
configuration contribution to heat capacity obtained in this work is consistent with the assessment,
calculated from the difference between the experimental heat capacity and vibrational
contribution to it.
About the Author
Владимир ЯшкичевRussian Federation
References
1. Flubacher P., Leadbetter A., Morrison J. // J. Chem. Phys. - 1960. - V.33. - P.1751.
2. Long E.A., Kemp J.D. // J. Amer. Chem. Soc. - 1936. - V. 58. - Р. 1829.
3. Эйзенберг Д., Кауцман В. Структура и свойства воды. - Л.: Гидрометеоиздат, 1975.
4. Яшкичев В.И. Вода. Движение молекул, структура, межфазные процессы, отклик на внешнее воздействие. - М.: Агар, 1998.
5. Haggis G.H., Hasted J.B., Buchanan T.J. // J. Chem. Phys. - 1952. - V. 20. - P.1452.
6. Nemethy G. Scheraga H.A. // J. Chem. Phys. - 1962. - V. 36. - P.3382.
7. Grjotheim K. Krogh-Moe // J. Acta Chem, Scand. - 1954. - V.8. - P.1193.
8. Walrafen G.E. // J.Chem.Pys. - 1966. - V.44. - P.1546
9. Пиментел Д., Мак-Клеллан О. Водородная связь. - М.:Мир, 1964.